Nitrites and their mixtures. WebIf a type 3 vessel carrying Class 1 DG on board would staying over-night at the WDGA, notification in writing to the Dangerous Goods Unit of the Marine Department will need to be given. Although there are different degrees of separation of dangerous goods Subsection 2.2(4) and Parts 9 and 10 of the TDG Regulations authorize you to use the classification from the: Many substances in Schedule 1 are assigned one or more packing groups. WebProduct Name Mercury(II) sulfate Cat No. The type of packaging and destination marks may be entered in any appropriate manner before or after the basic description. Flammable Gases 3. As per subsection 11.1(1) of the TDG Regulations, the IMDG Code must be consulted for international transport by ship. Classification is defined in Part 1 of the TDG Regulations as: classification means, for dangerous goods, as applicable, the shipping name, the primary class, the compatibility group, the subsidiary class, the UN number, the packing group, and the infectious substance category.. For information on COVID-19 updates, please visit Canada.ca/coronavirus. Some dangerous goods have multiple hazards. You may experience longer than usual wait times or partial service interruptions. Only required when a marine pollutant is being transported in a means of containment on a vessel. Other dangerous goods safety marks that may be required for a shipment of dangerous goods are summarized in Table 2 below. See Section 2.5. ), 2. 1. The packing group for a dangerous good is determined by using the laboratory test data and comparing it to the criteria in Part 2. Admin. Note: This document is a general overview of the TDG classification requirements. Which one is the correct one? (vii) for dangerous goods that are subject to special provision 23, the words toxic by inhalation or toxic inhalation hazard or toxique par inhalation or toxicit par inhalation; Examples of classification descriptions of dangerous goods are: UN1214, ISOBUTYLAMINE, Class 3, Subsidiary Class (8), II, UN1214, ISOBUTYLAMINE, Class 3(8), Packing Group II, UN3381, TOXIC BY INHALATION LIQUID, N.O.S., Class 6.1 PG I, UN 1075 LIQUEFIED PETROLEUM GASES (propane); Not odourized, Class 2.1. Admin. 120.790 - 120.790 - Advance Notification of Shipment of Nuclear Waste, 180 Neb. What are the requirements for dangerous goods safety marks when displayed on the means of containment. Subscribe to Free Newsletter For example, if you have a product for which you determined that the shipping name will be FLAMMABLE LIQUID, N.O.S. The data below is an example showing UN1203, GASOLINE. Abbreviations may be used for indicating packaging types (for example, cyl. for cylinder) provided the abbreviations are commonly accepted and recognizable. in the case of infectious substances, a doctor, scientist, veterinarian, epidemiologist, genetic engineer, pathologist, nurse, coroner, or laboratory technologist or technician. If the dangerous goods are biohazardous substances (Class 6.2), the consignor may use the classification determined by Health Canada or the Canadian Food Inspection Agency. International Civil Aviation Organization (ICAO) Technical Instructions for the transport of dangerous goods by air, International Maritime Dangerous Goods (IMDG) Code for the transport of dangerous goods by ship, or. Trade name is not accepted. Mercury and its compounds. The technical name shall be a recognized chemical or biological name, or other name currently used in scientific journals and handbooks. hazard class, classified in Class 6.1, Toxic substances that are listed in Special Provision 23, classified in Class 7, Radioactive materials that require a Cat III Yellow label. Mercury. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Select country for which that subsidiary belongs to. Go to Setup > company > Subsidiaries. if applicable, the technical name of the dangerous goods, the classification of the dangerous goods, and. White asbestos (chrysotile, actinolite, anthophyllite, tremolite), Dangerous Goods of Class9, Packing Group III, Liquids, not listed above, Dangerous Goods of Class9, Packing GroupIII, Solids, not listed above. Services Main Page. Some of the classes can be further divided into divisions, e.g., Class 1, while others do not have sub-divisions, e.g., Class 3. ?O.Q\tF,"V4Iuu8jhb7ew?NI ~eS^lsEU_{\3>e; F]u:MvF7Bz3Jz;O>tzw5qy:!&|]&$fG6F`B@a'\` Eno14}tQ`?K4%1nFh,D_Qg4f>~j $7NH s:o~P;v4fRd%r{6|;>v&K >Z!O~X}u!wv=@~0}$vN=. If the dangerous good is an explosive or radioactive material, it must be classified as required by other regulatory authorities. It can also negatively affect reproductive health. Classification can be done by a consultant or a competent employee who has been trained in TDG classification. Transportation of Dangerous Goods (TDG) - Dangerous Goods Safety Marks (Road), All Admin. Class 4 Substances/Products include: Flammable Solids; Substances Liable to Spontaneous Combustion; Substances That on Contact with Water Emit Flammable Gases (Water-reactive Substances), Class 5 Oxidizing Substances, including Organic Peroxides, Class 9 Miscellaneous Products, Substances or Organisms. ; UN 1224, KETONES, LIQUID, N.O.S, Example: UN 1993 FLAMMABLE LIQUIDS, N.O.S. Are safety marks required on consolidation bins? :), How to Assign UN Packing Group for Dangerous Goods. UN3091 or UN3481, as appropriate for lithium cells or batteries that are contained in, or packed with equipment. Class1.1, 1.2, 1.3 or 1.5 explosives that are: not subject to Special Provision 85 or 86 and the quantity is less than or equal to 10 kg, or, subject to Special Provision SP 85 or 86 and the quantity is less than or equal to 1000 articles (note: this is number of articles, not mass), Class 1.4 (except Class 1.4S) is 1000 kg or less, Class 6.1 and are not required to comply with Special Provision 23, Class 6.1 but are not an inhalation hazard and are not listed in Special Provision 23. capacity of each cylinder is greater than 225 L, are interconnected through a piping arrangement, and, are permanently mounted on a structural frame for transport, Class 6.1 for exposure to other routes (not an inhalation hazard)and are not listed in Special Provision 23, Class 6.1, Toxic Substances due to inhalation toxicity, Are dangerous goods subject to Special Provision 23. Gross quantity of Class 1.4 (except Class 1.4S) is 1000 kg or less, Class1.1, 1.2, 1.3 or 1.5 explosives that are not subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 10 kg, Class1.1, 1.2, 1.3 or 1.5 explosives that are subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 1000 articles. The alphabetical order has been determined by ignoring all numerical digits and all lower case letters that precede the first capital letter in the shipping name. `9yYcQKL U\ >5Iy+&1fXM+DD.> vl=|TOZg]-L8o1016&nY#Xh*4z5tGLUlWi. The following state regulations pages link to this page. Consult Schedule 3 for the shipping name that most precisely describes the dangerous goods. 33, Part XV, 1519 - 1519 - Advance Notification of Shipment of Irradiated Reactor Fuel and Nuclear Waste [Formerly 1516], 10 144 Me. Yes. The Primary class is shown first, with the subsidiary classes in brackets. Except for Class 1, Explosives; UN numbers are only required for: those dangerous goods that must have an ERAP dangerous goods that are liquid or gas in direct contact with the large means of containment. Note: The NA numbers in the 49 CFR are not permitted in Canada. Hazard class (the primary class and possible subsidiary class/es), Packing group, compatibility group, or the infectious substance category for biohazardous substances, SHIPPING NAME (in Column 2 of Schedule 1): GASOLINE; MOTOR SPIRIT; or PETROL (when selecting the shipping name you can use one of the three listed names such as gasoline), Hazard Class (in Column 3 of Schedule 1): 3, Identification Number (in Column 1 of Schedule 1): UN1203, Packing Group (in Column 4 of Schedule 1): II, UN1096 SIGNALS, SMOKE which is not allowed to be transported on a ship. This sign must be displayed at or next to each entry way of the large means of containment (greater than 450 L) when the containment is fumigated with a dangerous good. This communication is accomplished by the: Note that the difference between labels and placards is their size. What safety marks are required on a large means of containment (capacity 450L or more)? (iii) For domestic shipments, primary and subsidiary hazard class or division names may be entered following the numerical hazard class or division, or following the basic description. (iii) The following are excepted from the requirements of paragraph (a)(5) of this section: (A) Bulk packages, provided some indication of the total quantity is shown, for example, 1 cargo tank or 2 IBCs., (B) Cylinders, provided some indication of the total quantity is shown, for example, 10 cylinders.. A substance, mixture, or article that is a marine pollutant and does not meet the classification criteria for inclusion in any other hazard class shall be declared under either UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, n.o.s. (gasoline). Products and For example, both gasoline and diesel are listed by their name in Schedule 1. The letters UN must not be included with the number when the UN number is displayed on the primary class label. Dangerous goods safety marks are the first line of communication about the hazard(s) of the dangerous good. Class 1 (explosives) materials; self-reactive substances; Division 5.2 materials; and entries that are not assigned a packing group (e.g., Class 7) are excepted from this requirement. The material's flash point will be displayed with the unit of measure and followed by "c.c." Determine the primary class, subsidiary class(es) and packing group by using section 2.8 - Precedence of Classes in Part 2, Classification. Laboratory tests are required for pure substances, solutions, and mixtures. N.O.S. Dangerous Goods of Class4.2, Packing Group III, not listed above, Magnesium powder or Magnesium alloys, powder, Dangerous Goods of Class4.3, Packing Groups I, not listed above, Aluminum smelting by-products or Aluminum remelting by-products, Phosphorus pentasulphide, free from yellow and white phosphorus, Dangerous Goods of Class4.3, Packing Groups II, not listed above, Calcium cyanamide, with more than 0.1% Calcium carbide, Ferrosilicon, with 30% or more but less than 90% silicon, Magnesium granules, coated, particle size not less than 149mm, Dangerous Goods of Class4.3, Packing Group III, not listed above, Ammonium nitrate, liquid, hot concentrated solution, Hydrogen peroxide, stabilized or Hydrogen peroxide, aqueous solutions, stabilized, with more than 60% hydrogen peroxide, Dangerous Goods of Class5.1, Packing Group I, not listed above, Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water, Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts, Hydrogen peroxide, aqueous solution, with more than 40% but not more than 60% hydrogen peroxide, stabilized, as necessary, Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 40% hydrogen peroxide, stabilized, as necessary, Potassium nitrate and sodium nitrite mixture, Dangerous Goods of Class5.1, Packing Group II, not listed above, Dangerous Goods of Class5.1, Packing GroupII, Solids, not listed above, having no subsidiary class other than Class9, Dangerous Goods of Class5.1, Packing GroupIII, Liquids, Dangerous Goods of Class5.1, Packing GroupIII, Solids, Dangerous Goods of Class5.2, Packing GroupI, Dangerous Goods of Class5.2, Packing GroupII, Dangerous Goods of Class5.2, Packing GroupIII, Hydrocyanic acid, aqueous solution, with not more than 20% hydrogen cyanide, Hydrogen cyanide, solution in alcohol, with not more than 45 percent hydrogen cyanide, Hydrogen cyanide, stabilized, containing less than 3% water, Methyl bromide and ethylene dibromide mixture, liquid, Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23C (73F), Toxic by inhalation, liquid, n.o.s., with an LC, Toxic by inhalation, liquid, flammable, n.o.s., with an LC, Toxic by inhalation, liquid, water reactive, n.o.s., with an LC, Toxic by inhalation, liquid, oxidizing, n.o.s., with an LC, Toxic by inhalation, liquid, corrosive, n.o.s., with an LC, Dangerous Goods of Class6.1, Packing GroupI, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupI, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupII, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, Liquids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, Solids, not listed above, Dangerous Goods of Class6.1, Packing GroupIII, not listed above, with a subsidiary classification other than 9, Chlorosulphonic acid, with or without sulphur trioxide, Hydrazine, aqueous solution, with more than 37% hydrazine, by mass, Hydrazine, aqueous solution, flammable with more than 37% hydrazine, by mass, Hydrofluoric acid and sulphuric acid mixture, Hydrofluoric acid solution, more than 60% hydrogen fluoride, Nitrating acid mixtures, more than 50% nitric acid, Nitric acid, other than red fuming, with more than 70% nitric acid, Sulphuric acid, fuming, greater than or equal to 30% free sulphur trioxide, Sulphuric acid, fuming, less than 30% free sulphur trioxide, Dangerous Goods of Class8, Packing GroupI, not listed above, Battery fluid, acid or Sulphuric acid, with not more than 51% acid, Formic acid, with more than 85% acid by mass, Hydrofluoric acid solution, not more than 60% hydrogen fluoride, Nitrating acid mixtures, not more than 50% nitric acid, Nitric acid, other than red fuming, with not more than 70% nitric acid, Dangerous Goods of Class8, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class8, Packing GroupII, Solids, not listed above, Dangerous Goods of Class8, Packing GroupIII, Liquids, not listed above, Dangerous Goods of Class 8, Packing Group III, Solids, not listed above, Dangerous Goods of Class9, Packing GroupI, Liquids, Dangerous Goods of Class 9, Packing Group I, Solids, Blue asbestos (crocidolite) or Brown asbestos (amosite, mysorite), Dangerous Goods of Class9, Packing GroupII, Liquids, not listed above, Dangerous Goods of Class 9, Packing Group II, Solids, not listed above. sponsor this page to leave your contact info on this page.. NOTE: The size of the Inhalation hazard letters vary for different types of means of containment. (b) Except as provided in this subpart, the basic description specified in paragraphs (a)(1), (2), (3), and (4) of this section must be shown in sequence with no additional information interspersed. Product usage (e.g., pesticide, adhesive, fuel, etc. the other class that further identifies the hazards of the dangerous goods. It exists in three forms that have different properties, usage, and toxicity. when all of the dangerous good safety marks can be seen through the overpack for each class of dangerous goods that is inside it, no additional labels or safety marks are required. The ICAO Technical Instructions, as well as Part 12, Air, of the TDG Regulations must be consulted for all shipments by air. In addition -. It is used for dangerous goods that do not have a specific entry by name in Schedule 1. (contains Xylene and Benzene), 3, II. Elevated temperature solid, n.o.s., at or above 240C (464F). Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers Solids containing flammable liquid, n.o.s. Other requirements may be listed in other sections, regulations, Codes, or Acts that are not listed in this table. More than one subsidiary class is possible. (cadmium sulfide, isodecyl diphenyl phosphate), 9, III, Marine Pollutant. How do I determine the compatibility group? Methylmercury and other organic compounds. Read More: Marine Pollutants & Environmentally Hazardous Substances: Definition, Marking and Exceptions. Subsidiary: In NetSuite each subsidiary record should be assigned with the nexuses in which it must pay taxes. There are 4 types of entries consisting of UN numbers and proper shipping names in the Dangerous Goods List. Toxic & Infectious 7. Code 5-3-25.4 - 410 IAC 5-3-25.4 - Advance notice of transport of nuclear waste, Kan. Admin. Class 2.1 Dangerous Goods Inhalation Hazard words for Class 6.1 and Class 2.3 dangerous goods, Category B Mark for UN3373 dangerous goods, Package certification marks (if required), Placard for the primary hazard class on each side and each end (total of four) for each dangerous good. as appropriate. How does the consignor determine the classification for a dangerous good? There are 9 dangerous goods classes. This mark must be displayed on one side of a means of containment. These are the primary class 2.3 and two subsidiary hazard classes 5.1 and 8. ), 4. EDT. The metal is obtained by heating cinnabar in a current of air and condensing the vapour. For example, UN3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. has three hazard classes assigned to it in Column 3 of Schedule 1. A proof of classification is a document that the consignor must provide, upon request, to the federal Minister of Transport. It can cause genetic deformities and alteration in the genetic material of a person. WebIdentification Product Name Mercury (Certified ACS) Cat No. Are there other requirements for labels on a small means of containment? Placards are not required or are optional for some dangerous goods when the gross quantity of the dangerous goods is 500 kg or less. WebSubsidiary Hazard Class6.1 Packing Group III IMDG/IMO UN-No UN2809 Proper Shipping Name Mercury Hazard Class 8 Subsidiary Hazard Class6.1 Packing Group III 15. Use the shipping name and its corresponding data (UN number, class, packing group/category) in Schedule 1 to assign the classification to the dangerous good. 619 of 2001 Notation Ceiling-C Ceiling value is a limit value above which exposure hbbd``b`$@@YD$;! Shipping Name and Description This column gives the shipping names for dangerous goods in alphabetical order within each primary class and within each packing group. Mercury is a highly toxic metal and can cause skin irritation, skin rashes, allergic reactions. Inorganic mercury compounds. See Section 1.17.1 in the TDG Regulations. Products and (4) The packing group in Roman numerals, as designated for the hazardous material in Column (5) of the 172.101 table. (v) the subsidiary class or classes, in parentheses, which may be shown as a number only or under the heading subsidiary class or classe subsidiaire or following the words subsidiary class or classe subsidiaire, except that, for transport by aircraft or by ship, the subsidiary class or classes may be shown after the information required by this paragraph, (vi) the packing group roman numeral, which may be shown under the heading PG or GE or following the letters PG or GE or following the words Packing Group or Groupe d'emballage, and. 6 CCR 1007-1 Part 17 - 6 CCR 1007-1 Part 17 - RADIATION CONTROL - TRANSPORTATION OF RADIOACTIVE MATERIALS, GA Reg. The most appropriate designation for the dangerous goods must be selected based on each class, UN number and packing group established per the classification requirements of clause 4.5. Mercury is a naturally occurring trace metalloid element and known neurotoxin with atomic symbol Hg, atomic number 80, and atomic weight 200.59. Packing Group This column gives the packing groups of the dangerous goods. Code 246-231-140 - 246-231-140 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. Column 4 Subsidiary Risk(s) Contains the class number(s) of any subsidiary risk(s). Solutions or Mixtures: When a solution or a mixture consists of one dangerous good mixed with non-dangerous goods (e.g., water) and the properties for the solution are the same as for the pure substance, the shipping name is followed by the word solution or mixture as applicable. Dangerous goods that can be shipped under this exemption will have a limited quantity index greater than 0 in Column 6(a) of Schedule 1 of the TDG Regulations. Note: The information below is provided as guidance only. WebListing, classification and packing Mercury (UN 2809): Subsidiary risk 6.1 Transmitted by the expert from Germany Introduction 1. Regulatory information United States of America Inventory Component CAS-No TSCA TSCA Inventory notification - Active/Inactive TSCA - EPA Regulatory Flags Mercury What information is needed for classification? The picture below shows hazard symbols for Class 4 dangerous goods. Azides. However, the safety mark requirements for large means of containment with a capacity of greater than 450 L but less than or equal to 3000 L (i.e., an intermediate bulk container) are: Placards are not required for overpacks as the definition and description for an overpack does not include large means of containment. Determine the shipping name: Check if the product name is listed in Schedule 1 or Schedule 3. Have the answers at your fingertips. The size (i.e., capacity) of the means of containment itself also determines whether a label or placard is required. The subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. What safety marks are required on a small means of containment (capacity 450L or less)? What types of other dangerous goods safety marks may be required? This placard is not mandatory, but it is permitted on a large means of containment (greater than 450 L) instead of any other placard when the containment has: - one or more dangerous goods that require different hazard class placards, - the dangerous goods are contained in two or more small means of containment, AND - the shipment consists of only the following dangerous goods classified in: NOTE: The TDG Regulations has specified circumstances when this placard is not allowed to be used. The Proper Shipping Name shall be supplemented with "MOLTEN"; Stabilized substances: WebThe subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. "6%X3$dl@7H,d100K@ ^/ (d) Technical and chemical group names may be entered in parentheses between the proper shipping name and hazard class or following the basic description. Generally, a large means of containment must have four placards (one on each side, one on the front and one in back). An appropriate modifier, such as contains or containing, and/or the percentage of the technical constituent may also be used. (a) The shipping description of a hazardous material on the shipping paper must include: (1) The identification number prescribed for the material as shown in Column (4) of the 172.101 table; (2) The proper shipping name prescribed for the material in Column (2) of the 172.101 table; (3) The hazard class or division number prescribed for the material, as shown in Column (3) of the 172.101 table. If the product's name is listed only in Schedule 3, use the UN number from Column 3 in this schedule to look up the product in Schedule 1. (2) Hazardous materials and hazardous substances transported by highway considered household wastes as defined in 40 CFR 261.4, and not subject to the Environmental Protection Agency's hazardous waste regulations in 40 CFR parts 262 and 263, are excepted from the requirements of this paragraph. This requirement is outlined in Part 5 of the TDG Regulations. Information on how to do the assignment is provided in Section 2.36 of Part 2. Subscribe to Free Newsletter We do not provide consultancy services. Admin. Wastes: If the product is a waste, then the shipping name is either preceded or followed by the word waste. Transport Canada is closely monitoring the COVID-19 situation. In this article, we will share with you some rules you need to follow when choosing UN numbers and proper shipping names. 1289 0 obj <>/Filter/FlateDecode/ID[]/Index[1273 31]/Info 1272 0 R/Length 79/Prev 99077/Root 1274 0 R/Size 1304/Type/XRef/W[1 2 1]>>stream If a substance is included in more than one class or packing group, its classification is determined in the following manner: << Note 3: The containers inside the package not required to bear TDG safety marks. I, II or III) assigned to the substance or article. If you like this article, please share it. WebClass 1 Explosives; Class 2 Gases; Class 3 Flammable liquids; Class 4 Other Flammable Substances; Class 5 Oxidizing Substances & Organic Peroxides; Class 6 Explosives 2. The labels must be displayed on any side of the outer surface of a means of containment other than the side on which it is intended to rest or be stacked during transport. WebClassifying Substances That Are Included in More Than One Class or Packing Group. Ch. Note 4: As the dangerous good is not identified with UN3373, the Category B mark is not required. endstream endobj startxref WebSubsidiary hazards must also be listed with the Basic Description. Generic risk (e.g., flammable, toxic, etc.). (7) The number and type of packages must be indicated. Flammable Liquids 4. symbol (e.g., explosion, flames, corrosion, etc. See Column 4 in Schedule 1. Figure 2: Safety marks on a small means of containment such as a package Note 1: The orientation marks for liquids are optional for road transport, but mandatory for air transport. It can cause headaches, can damage the nervous system of the body. Generally, the shipping name should be selected in the following hierarchical order: 1. We do not provide consultancy services. : M141-1LB; M141-6LB Synonyms Colloidal mercury; Hydrargyrum; Metallic mercuryRecommended Use The solution or mixture is mentioned by name in the Dangerous Goods List; The name mentioned only applies to the pure substance; The hazard class or division, subsidiary risk, packing group or physical state of the mixture or solution is different from that of the substance mentioned; The hazard characteristics and properties of the mixture require different emergency response measures; Is it a pure substance or well-defined mixture (by use) or well-defined article? Also, regardless of the quantity of dangerous goods on board, the primary class placard for each of the dangerous goods in a large means of containment must be displayed on each side and on each end of the large means of containment or means of transport. Proper shipping name is the standard technical name to describethe hazard properties and the composition of dangerous goods. Wis. Admin. WebEach subsidiary must be associated with at least one nexus. Classification is normally done by (or in consultation with): If you are the manufacturer of the product, the product must be tested according to Part 2 of TDG Regulations. CCOHS is not liable for any loss, claim, or demand arising directly or indirectly from any use or reliance upon the information. Dangerous goods that can be shipped under this exemption will have an excepted quantity code of E1, E2, E3, E4, or E5 in Column 6(b) of Schedule 1 of the TDG Regulations.
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